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Pention-S72-20wt% Solution 阴离子型膜溶液

  • 产品代码:1802006
  • 产品描述:Pention-S72-20wt% Solution
  • 品牌:SCI Materials Hub
  • 货期:2周
  • 浏览次数:
  • 咨询电话:+86 130-0303-8751
  • 关键词:Pention-S72-20wt% Solution, 阴离子型膜溶液, 离聚物, SCI Materials Hub, 科学材料站
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科学材料站(SCI Materials Hub)提供各种分散液和膜溶液产品,可用于燃料电池、电解槽、电池和其他电化学设备。分散液和膜溶液可用于制造不同厚度的自支撑和机械增强膜。催化气体扩散电极也可以利用这些分散液和膜溶液。


Pention系列分散液(也称为离聚体溶液)是高导电性和稳定的液体溶液,因此可用于包含阴离子交换膜(AEM)的电极层中。分散液结构为聚降冰片烯主链,以官能化和非官能化两种形式出售。官能化聚合物用季铵盐基团官能化,作为用于电极层的分散液出售(例如制备用于催化气体扩散层或气体扩散电极GDE等的催化剂油墨或浆液)。官能化聚合物不溶于传统溶剂体系,因此对于膜浇铸,非官能化聚合物溶解在有机溶液中,并且必须在膜制作步骤之后进行官能化。无功能聚合物以溶液形式出售。产品名称中的“D”代表分散液,“S”代表膜溶液。分散液是一种离子导电材料,可以按收到的形式使用。另一方面,解决方案目前正以非官能化的形式提供,用这些解决方案制造的产品需要官能化,以使其具有离子导电性。下图为季铵改性聚降冰片烯聚合物的化学结构。


图片7.png


Pention-S72-5wt%/10wt%/20wt%是在有机溶剂中聚合物浓度分别为5wt%、10wt%、20wt%的无功能阴离子溶液。该聚合物溶液均属于S72系列。其IEC(meq/g)为0,因为其非功能化形式,根据功能化程度,可以很容易地获得IEC(meq/g)为1-3.5的功能溶液。非功能化聚合物溶液产品很适合制造不同厚度值的自支撑膜或机械增强膜。膜形成后,需要对其进行官能化,以便传导离子(阴离子)。功能化程序可以在美国可再生能源实验室,南卡罗来纳大学和乔治亚理工学院联合进行的研究中找到。


Pention系列阴离子膜溶液可用于各种电化学应用,包括燃料电池、电解槽、传感器、流动电池和各种其他电化学应用/技术。用Pention树脂制成的膜显示了AEM燃料电池的最高记录性能,峰值功率密度为3.4 W/cm2(美国可再生能源实验室、南卡罗来纳大学和乔治亚理工学院联合开展的研究,研究原文见文末或本站下载中心)。所述的电化学性能数据仅供参考,并取决于MEA、CCM或GDE制造方法、使用的膜厚度、测试硬件设计和测试硬件中使用的组件以及操作参数(温度、压力、反应物流速等),这些值可能会或可能不会达到。


Pention系列分散体(也称离聚物)的主要优点:

非常高的导电性

化学稳定性高

亲水性或疏水性取决于所选系列的分散产品


Pention产品性能表:

PolymerIEC(meq/g)Water uptakeSwelling
GT181.1315%10%
GT351.8863%36%
GT753.54103%68%

Solutions are not functionalized;you have functionalize after making mermbrane.We use trimethylamine solution for functionalization.

请注意,科学材料站(SCI Materials Hub)的Pention系列分散剂含有溶剂,如果溶剂长时间直接接触瓶盖,可能会破坏瓶子的密封。我们建议在收到货物后立即将瓶子直立存放,以减少意外泄漏的可能性。


如有需求,请联系我们的团队。

Solvay Aquivion Dispersions
FormLiquid
Polymer Concentration20 wt%
Solvent SystemOrganic (undisclosed)
Total Acid Capacity0 meq/g in the unfunctionalized form and 1 to 3.5 meq/g in the functionalized form (Internal Method)
HSE/Transport ClassificationCorrosive/Hazardous


Pention solutions are the unfunctionalized dissolved polymer resin products that are used to manufacture anion conducting self-supporting membranes or mechanically reinforced membranes. The polymer structure contains a poly(norbornene) backbone and is sold in either functionalized and non-functionalized forms. The functionalized polymer is sold as a dispersion for use in electrode layers and is functionalized with a quaternary ammonium group. Functionalized dispersion products can be found here.

The functionalized polymer is not soluble in conventional solvent systems, so for membrane casting the unfunctionalized polymer is dissolved in solution and must be functionalized after membrane manufacture. The unfunctionalized polymer is sold in the solution form. "D" in the product name stands for dispersion and "S" in the product name stands for solution. Dispersions are ionically conducting materials and ready to be used in the as is form. Solutions, on the other hand, are currently being supplied in the unfunctionalized form and the products made with the solutions needs to be functionalized in order to make them ionically conductive. Chemical composition of the quaternary ammonium modified poly(norbornene) polymer resin is provided below.


Pention-S72-20wt% is an unfunctionalized solution with 20wt% polymer concentration in an organic solvent. This polymer solution belongs to S72 series. This product has an IEC (meq/g) of 0 in for its unfunctionalized form and depending on the level of functionalization, IEC of 1 to 3.5 can easily be obtained. Unfunctionalized polymer solution products are highly suitable for manufacturing self-supporting membranes or mechanically reinforced membranes with different thickness values. After the formation of the membrane, it needs to be functionalized in order to conduct ions (anions). Functionalization procedure can be found in the jointly conducted study between NREL, University of South Carolina, and Georgia Institute of Technology.


Membranes with Pention resin have demonstrated the highest recorded AEM fuel cell performance with a peak power density of 3.4 W/cm2 (jointly conducted study between NREL, University of South Carolina, and Georgia Institute of Technology). The stated electrochemical performance data is for reference only and depending on the MEA, CCM or GDE manufacturing method, used membrane thickness, testing hardware design and components used in the test hardware, and operational parameters (temperature, pressure, reactant flow rates, etc.), those values may or may not be attained.


Key Advantages of Pention Solutions:

Enables to obtaines anion exchange membranes with very high conductivity
Great chemical stability
High performance for fuel cells and electrolyzers


Pention solutions/dispersions are considered hazardous items under DOT and IATA regulation. 125 mL and 250 mL solution/dispersions will incur a hazardous fee to accommodate the regulations based on the final shipping location (which is included in the pricing listed on the Fuel Cell Store product pages).


Please note that Pention solutions/dispersions contain solvents that may compromise the seals of the bottles if the solvents are left in direct contact with the lids for long periods of time. We recommend always storing the bottles in an upright orientation as soon as the shipment is received to lessen the likelihood of inadvertent leakage.


A typical lead time of 2-3 weeks is to be expected.

Partial references citing our materials (from Google Scholar)


二氧化碳还原

1. ACS Nano Strain Relaxation in Metal Alloy Catalysts Steers the Product Selectivity of Electrocatalytic CO2 Reduction

The bipolar membrane (Fumasep FBM) in this paper was purchased from SCI Materials Hub, which was used in rechargeable Zn-CO2 battery tests. The authors reported a strain relaxation strategy to determine lattice strains in bimetal MNi alloys (M = Pd, Ag, and Au) and realized an outstanding CO2-to-CO Faradaic efficiency of 96.6% with outstanding activity and durability toward a Zn-CO2 battery.


2. Front. Chem. Boosting Electrochemical Carbon Dioxide Reduction on Atomically Dispersed Nickel Catalyst

In this paper, Vulcan XC-72R was purchased from SCI Materials Hub. Vulcan XC 72R carbon is the most common catalyst support used in the anode and cathode electrodes of Polymer Electrolyte Membrane Fuel Cells (PEMFC), Direct Methanol Fuel Cells (DMFC), Alkaline Fuel Cells (AFC), Microbial Fuel Cells (MFC), Phosphoric Acid Fuel Cells (PAFC), and many more!


3. Adv. Mater. Partially Nitrided Ni Nanoclusters Achieve Energy-Efficient Electrocatalytic CO2 Reduction to CO at Ultralow Overpotential

An AEM membrane (Sustainion X37-50 Grade RT, purchased from SCI Materials Hub) was activated in 1 M KOH for 24 h, washed with ultra-purity water prior to use.


4. Adv. Funct. Mater. Nanoconfined Molecular Catalysts in Integrated Gas Diffusion Electrodes for High-Current-Density CO2 Electroreduction

In this paper (Supporting Information), an anion exchanged membrane (Fumasep FAB-PK-130 obtained from SCI Materials Hub (www.scimaterials.cn)) was used to separate the catholyte and anolyte chambers.

SCI Materials Hub: we also recommend our Fumasep FAB-PK-75 for the use in a flow cell.


5. Appl. Catal. B Efficient utilization of nickel single atoms for CO2 electroreduction by constructing 3D interconnected nitrogen-doped carbon tube network

In this paper, the Nafion 117 membrane was obtained from SCI Materials Hub.


6. Vacuum Modulable Cu(0)/Cu(I)/Cu(II) sites of Cu/C catalysts derived from MOF for highly selective CO2 electroreduction to hydrocarbons

In this paper, Proton exchange membrane (Nafion 117), Nafion D520, and Toray 060 carbon paper were purchased from SCI Materials Hub.


7. National Science Review Confinement of ionomer for electrocatalytic CO2 reduction reaction via efficient mass transfer pathways

An anion exchange membrane (PiperION-A15-HCO3) was obtained from SCI Materials Hub.


8. Catalysis Communications Facilitating CO2 electroreduction to C2H4 through facile regulating {100} & {111} grain boundary of Cu2O

Carbon paper (TGPH060), membrane solution (Nafion D520), and ionic membrane (Nafion N117) were obtained from Wuhu Eryi Material Technology Co., Ltd (a company under SCI Materials Hub).


9. Advanced Energy Materials Interatomic Electronegativity Offset Dictates Selectivity When Catalyzing the CO2 Reduction Reaction

The bipolar membrane (Fumasep FBM), carbon paper (SIGRACET 29BC, Freudenberg paper H23C2), ion exchange membrane (Nafion N117), and anion exchange membrane (Fumasep, FAA-3-PK-130) were all obtained from SCI Materials Hub.


10. Separation and Purification Technology *CO spillover induced by bimetallic xZnO@yCuO active centers for enhancing C–C coupling over electrochemical CO2 reduction

5 % Nafion solution was obtained through SCI Materials Hub.


11. National Science Review Confinement of ionomer for electrocatalytic CO2 reduction reaction via efficient mass transfer pathways

In this paper, PiperION-A5-HCO3 anion exchange resin, Fumion FAA anion exchange resin, PiperION-A15-HCO3 and FAA-3-50 were purchased from SCI Materials Hub.


12. Vacuum Controllable dual Cu–Cu2O sites derived from CuxAl-LDH for CO2 electroreduction to hydrocarbons

Nafion and carbon paper (TGPH060) were supplied through SCI Materials Hub.


13. Chemical Engineering Journal Coupling electrocatalytic CO2 reduction with glucose oxidation for concurrent production of formate with high efficiency

An AEM membrane (PiperION, purchased from SCI Materials Hub) was activated in 1 M KOH for 24 h, washed with ultra-purity water prior to use.


14. Chem Identification of Cu0/Cu+/Cu0 interface as superior active sites for CO2 electroreduction to C2+ in neutral condition

In this paper, Sustainion X37-50 Grade RT membrane and the MEA electrolyzer (CRRMEA1a, Figure S34) with 1cm2 active area were obtained from SCI Materials Hub.

电池

1. J. Mater. Chem. A Blocking polysulfides with a Janus Fe3C/N-CNF@RGO electrode via physiochemical confinement and catalytic conversion for high-performance lithium–sulfur batteries

Graphene oxide (GO) in this paper was obtained from SCI Materials Hub. The authors introduced a Janus Fe3C/N-CNF@RGO electrode consisting of 1D Fe3C decorated N-doped carbon nanofibers (Fe3C/N-CNFs) side and 2D reduced graphene oxide (RGO) side as the free-standing carrier of Li2S6 catholyte to improve the overall electrochemical performance of Li-S batteries.


2. Joule A high-voltage and stable zinc-air battery enabled by dual-hydrophobic-induced proton shuttle shielding

This paper used more than 10 kinds of materials from SCI Materials Hub and the authors gave detailed properity comparsion.

The commercial IEMs of Fumasep FAB-PK-130 and Nafion N117 were obtained from SCI Materials Hub.

Gas diffusion layers of GDL340 (CeTech) and SGL39BC (Sigracet) and Nafion dispersion (Nafion D520) were obtained from SCI Materials Hub.

Zn foil (100 mm thickness) and Zn powder were obtained from the SCI Materials Hub.

Commercial 20% Pt/C, 40% Pt/C and IrO2 catalysts were also obtained from SCI Materials Hub.


3. Journal of Energy Chemistry Vanadium oxide nanospheres encapsulated in N-doped carbon nanofibers with morphology and defect dual-engineering toward advanced aqueous zinc-ion batteries

In this paper, carbon cloth (W0S1011) was obtained from SCI Materials Hub. The flexible carbon cloth matrix guaranteed the stabilization of the electrode and improved the conductivity of the cathode.


4. Energy Storage Materials Defect-abundant commercializable 3D carbon papers for fabricating composite Li anode with high loading and long life

The 3D carbon paper (TGPH060 raw paper) were purchased from SCI Materials Hub.


5. Nanomaterials A Stable Rechargeable Aqueous Zn–Air Battery Enabled by Heterogeneous MoS2 Cathode Catalysts

Nafion D520 (5 wt%), and carbon paper (GDL340) were received from SCI-Materials-Hub.


6. SSRN An Axially Directed Cobalt-Phthalocyanine Covalent Organic Polymer as High-Efficient Bifunctional Catalyst for Zn-Air Battery

Carbon cloth (W0S1011) and other electrochemical consumables required for air cathode were provided by SCI Materials Hub.


7. SSRN Cr-induced improvement of structural stability of δ-MnO2 optimizes cycling stability of aqueous Zn-ion batteries

The Zn sheet (99.99%) was purchased from SCI Materials Hub.


8. Nature Communications Atomic-scale regulation of anionic and cationic migration in alkali metal batteries

The lithium metal disk (purity: 99.9%, diameter: 16 mm, thickness: 0.6 mm) was obtained from SCI Materials Hub.


9. Chemical Engineering Journal Zinc-based energy storage with functionalized carbon nanotube/polyaniline nanocomposite cathodes

CNTs were purchased from SCI Materials Hub.


10. ACS Nano Interfacial Chemistry Modulation via Amphoteric Glycine for a Highly Reversible Zinc Anode

Zn foil (>99.99%, 100 μm) was purchased from SCI Materials Hub.


11. ACS Nano High-Energy and Long-Lived Zn–MnO2 Battery Enabled by a Hydrophobic-Ion-Conducting Membrane

Zn foil (99.9%), carbon paper, and carbon felt were obtained from SCI Materials Hub.


12. Nature Communications Unravelling rechargeable zinc-copper batteries by a chloride shuttle in a biphasic electrolyte

Carbon cloth (CeTech W0S1011), PP membrane (Celgard 2300), Glass fiber (Whatman GF/A), anion exchange membrane (Fumasep FAB-PK-130), and cation exchange membrane (Nafion N-117) were purchased from sci materials hub.


13. PROCEEDINGS OF SPIE A dendrite-free and corrosion-suppressive metallic Zn anode regulated by the hybrid aqueous/organic electrolyte

Zn foil (99.9%, 100 μm thickness) was obtained from the SCI Materials Hub.


14. Journal of Alloys and Compounds Cr-induced enhancement of structural stability in δ-MnO2 for aqueous Zn-ion batteries

The Zn sheet (99.99%) and Whatman GF/D paper were available for purchase on on the SCI Materials Hub.


15. Small Multifunctional Umbrella: In Situ Interface Film Forming on the High-Voltage LiCoO2 Cathode by a Tiny Amount of Nanoporous Polymer Additives for High-Energy-Density Li-Ion Batteries

Carbon coating aluminum foils with a thickness of 16 µm were acquired from SCI Materials Hub.


电解水

1. International Journal of Hydrogen Energy Gold as an efficient hydrogen isotope separation catalyst in proton exchange membrane water electrolysis

The cathodic catalysts of Pt/C (20 wt%, 2–3 nm) and Au/C (20 wt%, 4–5 nm) were purchased from SCI Materials Hub.


2. Small Science Silver Compositing Boosts Water Electrolysis Activity and Durability of RuO2 in a Proton-Exchange-Membrane Water Electrolyzer

Two fiber felts (0.35 mm thickness, SCI Materials Hub) were used as the porous transport layers at both the cathode and the anode.


3. Advanced Functional Materials Hierarchical Crystalline/Amorphous Heterostructure MoNi/NiMoOx for Electrochemical Hydrogen Evolution with Industry-Level Activity and Stability

Anion-exchange membrane (FAA-3-PK-130) was obtained from SCI Materials Hub.


4. Chemical Engineering Journal Electronic configuration of single ruthenium atom immobilized in urchin-like tungsten trioxide towards hydrazine oxidation-assisted hydrogen evolution under wide pH media

The non-reinforced anion exchange membrane (AEM) of the coupled system was obtained from SCI Materials Hub (Fumasep FAA-3-50).


5. Cell Reports Physical Science Non-layered dysprosium oxysulfide as an electron-withdrawing chainmail for promoting electrocatalytic oxygen evolution

Nickel foam (NF) was offered by SCI Materials Hub (Wuhu, China), and was ultrasonicated in HCl solution, ethanol, and acetone in proper order before being used in electrochemical measurements.


6. Materials Today Catalysis Valence engineering via double exchange interaction in spinel oxides for enhanced oxygen evolution catalysis

Commercial Cu foam was purchased from SCI Materials Hub.


7. Advanced Functional Materials Elucidating the Critical Role of Ruthenium Single Atom Sites in Water Dissociation and Dehydrogenation Behaviors for Robust Hydrazine Oxidation-Boosted Alkaline Hydrogen Evolution

The nonreinforced anion exchange membrane (AEM) of the HzOR-assisted OWS system was purchased from SCI Materials Hub (Fumasep FAA-3-50).


8. ACS Omega Boosting Hydrogen Evolution through the Interface Effects of Amorphous NiMoO4–MoO2 and Crystalline Cu

Pt/C (20 wt %) was purchased from SCI Materials Hub.


9. SSRN The Dual Active Sites Reconstruction on Gelatin In-Situ Derived 3d Porous N-Doped Carbon for Efficient and Stable Water Splitting

Nafion D521 was purchased from SCI Materials Hub.


10. Molecules Interfacial Interaction in NiFe LDH/NiS2/VS2 for Enhanced Electrocatalytic Water Splitting

Carbon cloth (SCI Materials Hub) were employed as substrates for the in-situ formation of VS2 and NiS2/VS2 on its surface via hydrothermal synthesis.

燃料电池

1. Polymer Sub-two-micron ultrathin proton exchange membrane with reinforced mechanical strength

Gas diffusion electrode (60% Pt/C, Carbon paper) was purchased from SCI Materials Hub.


2. Polymer Development of rigid side-chain poly(ether sulfone)s based anion exchange membrane with multiple annular quaternary ammonium ion groups for fuel cells

Fumion FAA-3-solut-10 was obtained from SCI Materials Hub.


3. Journal of Power Sources Boosting the power density of the H3PO4/polybenzimidazole high-temperature proton exchange membrane fuel cell to >1.2 W cm-2 via the deposition of acid-based polymer layers on the catalyst layers

PBI resin (molecular weight: 60000, SCI Materials Hub), carbon paper 39BB (SGL Carbon), 70 wt% Pt/C (TANAKA) were obtained from SCI Materials Hub.


4. SSRN Bulky and Rigid Spiro-Adamantane-Fluorene Unit Promoted Microphase Separation in Di-Cation Side Chain Grafted Anion Exchange Membrane

Fumasep FAA-3-20 was obtained from SCI Materials Hub.


催化-ORR

1. J. Chem. Eng. Superior Efficiency Hydrogen Peroxide Production in Acidic Media through Epoxy Group Adjacent to Co-O/C Active Centers on Carbon Black

In this paper, Vulcan XC 72 carbon black, ion membrane (Nafion N115, 127 μL), Nafion solution (D520, 5 wt%), and carbon paper (AvCarb GDS 2230 and Spectracarb 2050A-1050) were purchased from SCI Materials Hub.


2. Journal of Colloid and Interface Science Gaining insight into the impact of electronic property and interface electrostatic field on ORR kinetics in alloy engineering via theoretical prognostication and experimental validation

The 20 wt% Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) were purchased from SCI Materials Hub. This work places emphasis on the kinetics of the ORR concerning Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) catalysts, and integrates theoretical prognostication and experimental validation to illuminate the fundamental principles of alloy engineering.


3. Catalysis Solution-Phase Synthesis of Co-N-C Catalysts Using Alkali Metals-Induced N-C Templates with Metal Vacancy-Nx sites

In this paper, PtRu-C (60 % PtRu (3.5nm) on High Surface Area Carbon, Pt:Ru = 1:1, SCI Materials Hub), an alkaline dispersion (PiperION-A5-HCO3-EtOH, 5 wt.%, SCI Materials Hub), anion exchange membrane (PiperION-A type-HCO3, SCI Materials Hub) were used as received.


电容器

1. Journal of Energy Storage Unraveling the detrimental crosstalk between cathode and anode in the aqueous asymmetric capacitor of activated carbon /copper oxide

In this paper, Fumasep FAA-3-50 anion exchange membrane (Thickness 50 μm, surface resistance 0.6–1.5 Ω cm−2, transference number 92–96 %) was bought from SCI Materials Hub.


催化加氢

1. Nature Communications Electrosynthesis of polymer-grade ethylene via acetylene semihydrogenation over undercoordinated Cu nanodots

In this paper, activated carbon (Vulcan XC-72) was obtained from SCI Materials Hub.


水处理

1. Water Research Electro-peroxone with solid polymer electrolytes: A novel system for degradation of plasticizers in natural effluents

In this paper, Nafion® N324 (SCI Materials Hub), between a 15 cm2 (3 cm × 5 cm) graphite plate anode and a graphite felt cathode (EP-SPE system)


表征

1. Chemical Engineering Journal Electrochemical reconstitution of Prussian blue analogue for coupling furfural electro-oxidation with photo-assisted hydrogen evolution reaction

An Au nanoparticle film was deposited on the total reflecting plane of a single reflection ATR crystal (SCI Materials Hub, Wuhu, China) via sputter coater.


理论计算

1. Sustainable Energy & Fuels A desulfurization fuel cell with alkali and sulfuric acid byproducts: a prototype and a model

A Fumasep®FKD-PK-75 membrane was used as the cation exchange membrane, in which the the oxygen permeability of membrane was about 1 cm3(STP)/(s cm2 cm Hg) [Ref. SCI Materials Hub]


器件

1. Journal of Materials Science: Materials in Electronics Preparation and application of electrical conductive composites with skin temperature-triggered attachable and on-demand detachable adhesion

Carbon black (CB, Ketjenblack EC 600JD) was purchased from SCI Materials Hub.


材料合成

1. Acta Materialia In situ epitaxial thickening of wafer-scale, highly oriented nanotwinned Ag on tailored polycrystalline Cu substrates

Single-crystal Cu (1 cm × 1 cm) substrates with a (111) orientation were purchased from SCI Materials Hub (www.scimaterials.cn).

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