
在电池材料研究中,很多关键反应并不是静态发生的。电极材料的相变、界面膜生成、电解液分解、中间产物演化以及活性物质结构变化,往往都发生在充放电过程中。传统拆解测试只能获得某一状态下的离线结果,而原位拉曼测试可以在电池运行过程中实时观察材料和界面变化,更适合用于研究反应机理、失效过程和电极结构演变。
Fueiceel® EC600a7 原位拉曼电池夹具是一款用于电化学原位拉曼表征的专用测试夹具。产品采用耐腐蚀钛池体、石英或蓝宝石光学窗口、PTFE / 氟胶密封结构和弹性加压组件,可用于锂离子电池、钠离子电池、金属负极电池、水系电池等多类型体系的原位拉曼测试。

EC600a7 采用紧凑型圆柱式电池夹具结构,中部为反应腔,顶部配置透光窗口,拉曼激光可通过窗口进入电池内部,直接采集靠近窗口一侧电极表面的拉曼信号。
夹具内部通过弹簧和金属垫片提供稳定压力,使正极、隔膜、负极保持良好接触;通过 O 型圈、PTFE 或氟胶垫片实现密封;通过两侧铜柱与外部电化学工作站连接,从而实现电化学测试与拉曼光谱采集同步进行。
| 项目 | 参数 |
|---|---|
| 产品型号 | Fueiceel® EC600a7 |
| 产品名称 | 原位拉曼电池测试夹具 |
| 池体材质 | 耐腐蚀钛 |
| 窗口材质 | 石英或蓝宝石 |
| 密封垫片 | PTFE 或氟胶 |
| 窗口直径 | Ø10 mm |
| 池体尺寸 | Ø52 mm × 高 24 mm |
| 反应腔内径 | Ø20 mm |
| 主要用途 | 多类型电池原位拉曼测试 |
EC600a7 可用于多种电池和电化学体系的原位拉曼研究,适合观察电极材料、电解液、界面膜和中间产物在电化学过程中的变化。
| 测试体系 | 典型研究方向 |
|---|---|
| 锂离子电池 | 正负极材料结构演变、嵌锂 / 脱锂过程、界面副反应 |
| 钠离子电池 | 钠离子嵌入机制、层状氧化物相变、硬碳负极界面变化 |
| 钾离子电池 | 大半径离子嵌入过程、电极结构稳定性研究 |
| 锂金属电池 | 锂沉积 / 剥离行为、SEI 膜生成、枝晶相关界面变化 |
| 钠金属电池 | 金属钠界面反应、沉积形貌与电解液分解研究 |
| 锂硫电池 | 多硫化物中间体演化、硫正极反应路径分析 |
| 水系锌离子电池 | 锌沉积、界面副反应、水系电解液结构变化 |
| 超级电容器 / 电化学电容器 | 电极表面吸附、离子传输与界面结构变化 |
| 电催化体系 | 催化电极表面中间体、吸附物种和反应路径研究 |
实际测试时,应根据电极尺寸、隔膜尺寸、电解液体系、窗口透光范围和反应腔空间进行合理装配。
EC600a7 由光学窗口组件、反应腔组件、电极装配组件、弹性加压组件、绝缘密封组件和外部导电组件组成。
| 模块 | 组成部件 |
|---|---|
| 光学窗口组件 | 窗口盖、石英 / 蓝宝石窗口、窗口密封垫片 |
| 反应腔组件 | 钛金属反应腔、O 型圈、反应腔密封槽 |
| 电极体系 | 正极片、隔膜、负极片 |
| 加压组件 | 金属垫片、弹簧 |
| 绝缘组件 | 绝缘柱、PTFE 垫片、T 型绝缘管 |
| 底部与导电组件 | 底座、紧固螺栓、铜柱导电端子 |
这种分模块排版比单独罗列所有零件更紧凑,也更适合详情页展示。
EC600a7 的测试核心是让拉曼激光通过顶部石英或蓝宝石窗口进入电池内部,照射到靠近窗口一侧的电极表面。随着电池充放电进行,拉曼光谱仪可以实时采集电极材料、界面产物或电解液相关物种的信号变化。
为了获得更有效的拉曼信号,靠近窗口的一侧电极建议优先选择自支撑电极,例如碳纸、碳布、金属网负载材料、泡沫金属负载材料等。自支撑电极不需要厚重集流体遮挡,激光更容易到达电极活性表面,也有利于提升原位信号的稳定性和可重复性。
如果使用常规涂布电极,应确保测试面朝向窗口,并尽量避免厚集流体、过厚涂层或不透明基底阻挡光路。
取出金属反应腔,找到腔体上端环形密封槽,将 O 型圈完整压入槽内。安装时应确认 O 型圈无扭曲、无翘起、无局部挤压。O 型圈状态会直接影响后续密封性能。
将装好 O 型圈的反应腔整体翻转,使窗口侧朝下平稳放置。此时反应腔内部朝上,便于依次装入电极和隔膜。
用镊子夹取正极片放入反应腔,使测试面朝向下方窗口。随后放入隔膜,确保隔膜完整覆盖正极表面。最后放置负极片,使正极、隔膜、负极三层材料居中对齐,避免边缘偏移或直接接触。
将绝缘柱垂直放入反应腔,使其与负极背面接触。再将金属垫片放入绝缘柱中心,最后放置弹簧。弹簧可以提供持续压力,使电极与隔膜保持紧密接触,降低界面阻抗。
在反应腔上端平面放置 PTFE 垫片,使孔位对齐。将底座金属板盖在垫片上方,确保底座与反应腔孔位完全对应,两侧铜柱朝外,方便连接测试设备。
每根紧固螺栓需先穿入 T 型绝缘管,以避免螺栓导通上下金属件造成短路。六根螺栓对准孔位后先手动旋入,初步固定即可,不建议单点一次性拧紧。
完成底部固定后,将夹具整体翻转,使窗口安装面朝上,准备安装光学窗口组件。
将石英或蓝宝石窗口放入窗口凹槽,铺设密封垫片,再盖上窗口盖。锁紧时建议采用对角分步拧紧方式,使窗口受力均匀,避免窗口破裂或密封不良。
组装完成后,使用万用表连接两侧铜柱进行短路检测。确认正负极之间无短路后,再进行电解液加注、静置浸润和后续电化学测试。
建议提前准备电极片、隔膜、电解液、镊子、移液器、螺丝刀、万用表、电化学工作站和拉曼光谱仪。对于空气敏感体系,例如金属锂、金属钠或部分高活性电解液体系,建议在手套箱内完成装配和密封。
靠近窗口一侧的电极会直接影响拉曼信号质量。建议优先选择自支撑电极,例如碳纸、碳布、泡沫镍、金属网或其他可承载活性材料且不明显遮挡激光的基底。对于粉末材料,可以将活性物质负载在自支撑导电基底上,使激光能够有效照射到目标反应区域。
若采用常规铝箔、铜箔涂布电极,应注意测试面方向,避免集流体位于光路一侧,否则可能导致拉曼信号明显减弱甚至无法采集到有效电极信号。
电解液加入量应以充分浸润电极和隔膜为原则,不宜过少,也不宜过量。电解液过少可能导致电化学接触不稳定;电解液过多则可能在窗口区域形成较厚液层,影响激光聚焦和信号采集。
将两侧铜柱分别连接电化学工作站正负极端。测试前建议先进行开路电压检查、阻抗测试或简单电压响应测试,确认电池连接正常后再进行正式原位拉曼采集。
将夹具窗口朝上放置在拉曼显微镜载物台上,调整焦距,使激光聚焦在窗口下方目标电极表面。测试时应根据材料特性选择合适激光波长、激光功率、积分时间和采集间隔。对于易受热材料,应降低激光功率,避免局部烧蚀或热诱导结构变化。
可用于观察层状氧化物、磷酸盐、尖晶石等正极材料在充放电过程中的结构变化,帮助分析材料相变、晶格畸变和可逆性。
适合研究钠离子嵌入 / 脱出过程,尤其适用于层状氧化物、普鲁士蓝类材料、硬碳负极等体系的结构演变分析。
可用于锂金属、钠金属、锌金属等负极体系的界面研究,包括沉积 / 剥离过程、电解液分解、SEI 或界面膜形成等。
可用于研究硫正极反应过程中的多硫化物生成、转化和迁移行为,为理解穿梭效应和反应路径提供光谱证据。
对于水系锌离子电池、水系钠离子电池等体系,可用于观察电解液溶剂化结构、界面副反应和电极表面产物变化。
| 注意事项 | 说明 |
|---|---|
| 密封件安装 | O 型圈和垫片必须平整放置,避免夹偏、折皱或破损 |
| 电极对齐 | 正极、隔膜、负极应居中,隔膜需完全覆盖电极 |
| 光路方向 | 需要采集信号的电极面应朝向窗口 |
| 电极选择 | 优先使用自支撑电极,有利于激光到达电极表面 |
| 螺栓锁紧 | 建议对角、分步、均匀锁紧,避免窗口受力不均 |
| 短路检查 | 每次测试前必须使用万用表确认无短路 |
| 激光功率 | 易受热材料应降低功率,避免热损伤 |
| 清洁维护 | 测试后及时清理电解液,窗口避免硬物刮擦 |
可用于锂离子电池、钠离子电池、钾离子电池、锂金属电池、钠金属电池、锂硫电池、水系锌离子电池、超级电容器以及部分电催化体系的原位拉曼测试。具体适配情况需结合电极尺寸、电解液兼容性和实验装配方式判断。
原位拉曼测试需要激光穿过窗口照射到电极表面。如果靠近窗口的一侧是厚集流体或不透明基底,信号会被遮挡。自支撑电极,如碳纸、碳布、泡沫金属或金属网负载电极,可以让激光更有效地到达活性材料表面,从而提高信号强度和测试稳定性。
石英窗口适合常规拉曼测试,透光性好,应用范围广。蓝宝石窗口机械强度和耐磨性更高,适合对窗口强度要求更高的实验条件。
EC600a7 的窗口直径为 Ø10 mm,可满足常规原位拉曼激光聚焦和信号采集需求。
反应腔内径为 Ø20 mm,适合装配小尺寸电极、隔膜和弹性加压组件。
原位电池夹具内部包含正极、隔膜、负极和金属导电组件。如果隔膜偏移、极片错位或绝缘管未正确安装,可能造成内部短路。每次测试前进行短路检测,可以降低实验失败和设备风险。
弹簧可以提供持续稳定的压力,使电极与隔膜保持良好接触,有助于降低界面阻抗,提高电化学测试稳定性。
可以依次检查以下因素:电极测试面是否朝向窗口,窗口是否清洁,激光焦点是否对准电极表面,电解液层是否过厚,电极基底是否遮挡光路,激光功率和积分时间是否合适。若条件允许,建议使用碳纸、碳布等自支撑电极提升信号采集效果。
钛金属池体、窗口盖、底座、铜柱、螺栓等结构件可重复使用。O 型圈、PTFE / 氟胶垫片、隔膜和电极片属于消耗件,建议根据实验情况定期更换。
测试完成后应及时拆解夹具,去除残留电极、电解液和隔膜。钛金属件可根据电解液类型选择合适溶剂清洁,窗口需轻柔擦拭,避免划伤。所有部件应完全干燥后再收纳。
Fueiceel® EC600a7 原位拉曼电池夹具是一款面向电池材料与电化学界面研究的原位测试工具。它通过耐腐蚀钛池体、石英 / 蓝宝石光学窗口、稳定密封结构和弹性加压系统,将电池运行过程与拉曼光谱采集结合起来,帮助研究人员实时观察电极材料、界面膜、电解液和反应中间体的变化。
对于锂离子电池、钠离子电池、金属负极电池、锂硫电池、水系电池以及其他新型储能体系,EC600a7 都可以作为原位拉曼测试平台,用于研究反应机理、材料结构演变和界面稳定性。
🛒 手机淘宝店铺:科学材料站
🔗 淘宝链接:点击进入淘宝网页
☎ 电话:+86 130-0303-8751 / +86 156-0553-2352
💬 微信:SCI-Materials-Hub
📧 Email 报价/对公需求:contact@scimaterials.cn
| 产品名称 | 型号 / 规格 | 配置说明 | 单位 | 价格 |
|---|---|---|---|---|
| 原位拉曼电池测试夹具 | EC600a7 标准版 | 耐腐蚀钛池体,石英窗口,PTFE / 氟胶密封垫片,铜柱导电端子,标准紧固组件 | 套 | 询价 |
| 原位拉曼电池测试夹具 | EC600a7 蓝宝石窗口版 | 标准夹具配置,窗口升级为蓝宝石窗口,适合更高强度测试场景 | 套 | 询价 |
| 石英窗口 | Ø24 mm | 用于 EC600a7 光学窗口更换 | 5片 | ¥200 |
| 蓝宝石窗口 | Ø24 mm | 高强度、高耐磨光学窗口 | 5片 | ¥400 |
| PTFE 密封垫片 | EC600a7 专用(2片0.3mmPTFE) | 用于窗口盖、反应腔、底座之间的绝缘与密封 | 套 | ¥50 |
| 氟胶密封垫片 | EC600a7 专用(2片0.3mm氟胶) | 适合需要弹性密封补偿的测试场景 | 套 | ¥50 |
| O 型圈 | EC600a7 专用 | 反应腔密封用,建议定期更换 | 5个 / 套 | ¥30 |
| 弹簧 | EC600a7 专用 | 提供稳定压紧力,保证电极与隔膜贴合 | 个 | ¥50 |
| 绝缘柱 | EC600a7 专用 | 用于内部绝缘支撑,防止短路 | 个 | ¥50 |
| T 型绝缘管 | EC600a7 专用(6个) | 配合紧固螺栓使用,防止上下金属件导通 | 套 | ¥60 |
| 铜柱导电端子 | EC600a7 专用(2个) | 用于连接电化学工作站正负极 | 个 | ¥10 |
| 紧固螺栓 | EC600a7 专用(12个) | 窗口盖、反应腔、底座锁紧固定用 | 套 | ¥60 |
部分使用和引用我们材料的参考文献 (摘自于Google Scholar)

二氧化碳还原
1. ACS Nano Strain Relaxation in Metal Alloy Catalysts Steers the Product Selectivity of Electrocatalytic CO2 Reduction
The bipolar membrane (Fumasep FBM) in this paper was purchased from SCI Materials Hub, which was used in rechargeable Zn-CO2 battery tests. The authors reported a strain relaxation strategy to determine lattice strains in bimetal MNi alloys (M = Pd, Ag, and Au) and realized an outstanding CO2-to-CO Faradaic efficiency of 96.6% with outstanding activity and durability toward a Zn-CO2 battery.
2. Front. Chem. Boosting Electrochemical Carbon Dioxide Reduction on Atomically Dispersed Nickel Catalyst
In this paper, Vulcan XC-72R was purchased from SCI Materials Hub. Vulcan XC 72R carbon is the most common catalyst support used in the anode and cathode electrodes of Polymer Electrolyte Membrane Fuel Cells (PEMFC), Direct Methanol Fuel Cells (DMFC), Alkaline Fuel Cells (AFC), Microbial Fuel Cells (MFC), Phosphoric Acid Fuel Cells (PAFC), and many more!
3. Adv. Mater. Partially Nitrided Ni Nanoclusters Achieve Energy-Efficient Electrocatalytic CO2 Reduction to CO at Ultralow Overpotential
An AEM membrane (Sustainion X37-50 Grade RT), purchased from SCI Materials Hub) was activated in 1 M KOH for 24 h, washed with ultra-purity water prior to use.
4. Adv. Funct. Mater. Nanoconfined Molecular Catalysts in Integrated Gas Diffusion Electrodes for High-Current-Density CO2 Electroreduction
In this paper (Supporting Information), an anion exchanged membrane (Fumasep FAB-PK-130 obtained from SCI Materials Hub (www.scimaterials.cn)) was used to separate the catholyte and anolyte chambers.
SCI Materials Hub: we also recommend our Fumasep FAB-PK-75 for the use in a flow cell.
5. Appl. Catal. B Efficient utilization of nickel single atoms for CO2 electroreduction by constructing 3D interconnected nitrogen-doped carbon tube network
In this paper, the Nafion 117 membrane was obtained from SCI Materials Hub.
In this paper, Proton exchange membrane (Nafion 117), Nafion D520, and Toray 060 carbon paper were purchased from SCI Materials Hub.
7. National Science Review Confinement of ionomer for electrocatalytic CO2 reduction reaction via efficient mass transfer pathways
An anion exchange membrane (PiperION-A15-HCO3) was obtained from SCI Materials Hub.
8. Catalysis Communications Facilitating CO2 electroreduction to C2H4 through facile regulating {100} & {111} grain boundary of Cu2O
Carbon paper (TGPH060), membrane solution (Nafion D520), and ionic membrane (Nafion N117) were obtained from Wuhu Eryi Material Technology Co., Ltd.
Note: Wuhu Eryi Material Technology Co. is a company hold by SCI Materials Hub.
9. Advanced Energy Materials Interatomic Electronegativity Offset Dictates Selectivity When Catalyzing the CO2 Reduction Reaction
The bipolar membrane (Fumasep FBM), carbon paper (SIGRACET 29BC, Freudenberg paper H23C2), ion exchange membrane (Nafion N117), and anion exchange membrane (Fumasep, FAA-3-PK-130) were all obtained from SCI Materials Hub.
10. Separation and Purification Technology *CO spillover induced by bimetallic xZnO@yCuO active centers for enhancing C–C coupling over electrochemical CO2 reduction
5 % Nafion solution was obtained through SCI Materials Hub.
11. National Science Review Confinement of ionomer for electrocatalytic CO2 reduction reaction via efficient mass transfer pathways
In this paper, PiperION-A5-HCO3 anion exchange resin, Fumion FAA anion exchange resin, PiperION-A15-HCO3 and FAA-3-50 were purchased from SCI Materials Hub.
12. Vacuum Controllable dual Cu–Cu2O sites derived from CuxAl-LDH for CO2 electroreduction to hydrocarbons
Nafion and carbon paper (TGPH060) were supplied through SCI Materials Hub.
13. Chemical Engineering Journal Coupling electrocatalytic CO2 reduction with glucose oxidation for concurrent production of formate with high efficiency
An AEM membrane (PiperION, purchased from SCI Materials Hub) was activated in 1 M KOH for 24 h, washed with ultra-purity water prior to use.
In this paper, Sustainion X37-50 Grade RT membrane and the MEA electrolyzer (CRRMEA1a, Figure S34) with 1cm2 active area were obtained from SCI Materials Hub.
微信公众号中文报道:Chem:基于热力学驱动的混合策略形成Cu0/Cu+/Cu0界面用于中性条件CO2电还原C2+
15. Surfaces and Interfaces Modulating surface microenvironment based on Ag-adorned CuO flower-liked nanospheres for strengthening C-C coupling during CO2RR
5 wt.% of Nafion solution, and N115 proton exchange membrane were procured with the help of SCI Materials Hub
16. ACS Appl. Energy Mater. Nanoporous Bismuth Induced by Surfactant-Modified Dealloying for Efficient Electrocatalytic Reduction of CO2 to Formic Acid
The anion exchange membrane (AEM, PiperION A20) and cation exchange membrane (CEM, Nafion 117) were obtained from SCI Materials Hub.
17. Adv. Energy Mater. Tailoring Microenvironments and In Situ Transformations of Cu Catalysts for Selective and Stable Electrosynthesis of Multicarbon Products
For GDE-based CO₂ electrolysis, the MEA reactor (CRRMEA5a, Sci-Materials Hub) consists of a titanium anode plate and a cathode plate with flow fields, along with insulating gaskets, integrated into a compression cell. The geometric area of each flow field is 5 cm² An anion exchange membrane (PiperION, A40-HCO3, Versogen) was used to separate the anode and the cathode.
18. Journal of Environmental Chemical Engineering Evaluation of electromethanogenesis in a microbial electrolysis cell using nylon cloth as a separator: reactor performance and metagenomic analysis
A commercial Nafion PEM (SCI Materials Hub) was used as the control to compare the electromethanogenesis performance.
CRRMEA1a 1cm2 MEA electrolyzer (Figure 4d) was obtained from SCI Materials Hub.
微信公众号中文报道:安徽师范大学最新Angew!全pH范围内铋基催化剂用于安培级电流密度电催化CO2还原
20. Separation and Purification Technology Coupling regulation of boron doping and morphology in nano-floral CuO using one pot method for electrocatalytic CO2 reduction
Carbon paper (TGPH060), Dupont Nafion solution (D520), and proton exchange membrane (N117) were acquired by SCI Materials Hub.
21. Chemical Engineering Journal Manipulating dual effects of morphology and oxygen vacancies through the incorporation of CuO onto CeO2 nanospheres for electrochemical CO2 reduction
Carbon paper (TGPH060), Dupont Nafion solution (D520), and proton exchange membrane (N117) were acquired by SCI Materials Station Hub (SCI Materials Hub, the same author as Ref. 20).
22. Advanced Materials Universal Formation of Single Atoms from Molten Salt for Facilitating Selective CO2 Reduction
The Nafion D520 dispersion and gas diffusion electrode (GDE, Sigracet, 39BB) were obtained from SCI Materials Hub (www.scimaterials.cn).
23. Science Bulletin Compressive strain in Cu catalysts: Enhancing generation of C2+ products in electrochemical CO2 reduction
CRRMEA1a 1cm2 MEA electrolyzer (Figure 3a) was obtained from SCI Materials Hub.
微信公众号中文报道:Science Bulletin:优化水覆盖度促进安培级电流密度下CO2还原C2+
Carbon paper (SGL CARBON, SGL36BB, purchased from SCI Materials Hub)
25. Chemical Engineering Journal In-situ reconstruction of active bismuth for enhanced CO2 electroreduction to formate
Anion-exchange membrane (Fumasep FAA-3–50) was purchased from SCI Materials Hub.
26. Nature Communications Bromide-mediated membraneless electrosynthesis of ethylene carbonate from CO2 and ethylene
Nafion D520 polymer binder solution (5 wt%) was purchased from SCI Materials Hub.
27. Ionics Sulfur-modified promoting the electrochemical CO2 reduction into formate performance of BiOI
Carbon black (Vulcan XC- 72, Cabot), teflon-treated carbon paper (TGP-H- 060, Toray), and proton exchange membrane (Nafion- 117) were purchased from SCI Materials Hub.
28. Nature Communications Continuous decoupled redox electrochemical CO2 capture
The anion exchange membrane (FAA-3-PK-75) with a thickness of 75 ± 5 μm was purchased from SCI Materials Hub.
29. Journal of Energy Chemistry Construction of efficient electrodes for CO2RR through microenvironment regulation of hydrophobic ionomer
An anion exchange membrane (PiperION-A15-HCO3, SCI Materials Hub) was used to separate the anode and cathode chambers.
30. Journal of Energy Chemistry The insights into ionomer-catalyst interactions enabling high-efficiency CO2 electroreduction in pure water
Methylimidazolium ionomer powder (Sustainion XA-9, dispersed in ethanol at 5 wt%), and piperidinium ionomer solution (PiperION A5, dispersed in ethanol at 5 wt%) were purchased from SCI Materials Hub (
31. ChemElectroChem Scaling CO Electrolyzers for Carbon-Neutral Chemical Synthesis
Specifically, the PTFE-CB ink was prepared by mixing 0.1 g of CB (Vulcan XC-72R, SCI Materials Hub) with PTFE (25 % of the CB mass) in 50 mL of methanol. After ultrasonication for 2 hours, the ink was air-sprayed onto the gas diffusion layer (GDL) (Sigracet 28 BC, SCI Materials Hub) at 60 °C. The anion exchange membrane (AEM) was Fumasep FAA-3-50 (SCI Materials Hub)
32. American Institute of Chemical Engineers Porous carbon-supported Ag catalysts enablehigh-current-density CO2 electroreductionto CO with enhanced mass transport
Carbon paper (SGL Sigracet 39 BB SGL Carbon), anion exchange membrane (Sustainion X37-50 Grade T, Dioxide Materials), Ni foam was obtained from SCI Materials Hub.
33. Applied Catalysis B: Environment and Energy Microenvironmental hydrophobicity-regulated evolution of reaction sites for boosting electrochemical CO2 reduction
A gas diffusion layer AvCarb GDS2240 was obtained from SCI MATERIALS HUB.
34. Applied Catalysis B: Environment and Energy Boosting seawater desalination driven by electroreduction of CO2 to formate on bimetallic Sn/Cu polyphthalocyanine frameworks
Gas diffusion layers (GDLs) consisting of Sigracet 36BB substrates (SCI Materials Hub) were utilized.
35. Catalysis Today Efficient and cost-effective electrocatalysts for coproduction of formate through electrocatalytic oxidation of PET-derived ethylene glycol coupled with CO2 reduction
Cation exchange membrane ((Nafion 117, DuPont) was purchased from SCI Materials Hub, China.
电池
1. J. Mater. Chem. A Blocking polysulfides with a Janus Fe3C/N-CNF@RGO electrode via physiochemical confinement and catalytic conversion for high-performance lithium–sulfur batteries
Graphene oxide (GO) in this paper was obtained from SCI Materials Hub. The authors introduced a Janus Fe3C/N-CNF@RGO electrode consisting of 1D Fe3C decorated N-doped carbon nanofibers (Fe3C/N-CNFs) side and 2D reduced graphene oxide (RGO) side as the free-standing carrier of Li2S6 catholyte to improve the overall electrochemical performance of Li-S batteries.
This paper used more than 10 kinds of materials from SCI Materials Hub and the authors gave detailed properity comparsion.
The commercial IEMs of Fumasep FAB-PK-130 and Nafion N117 were obtained from SCI Materials Hub.
Gas diffusion layers of GDL340 (CeTech) and SGL39BC (Sigracet) and Nafion dispersion (Nafion D520) were obtained from SCI Materials Hub.
Zn foil (100 mm thickness) and Zn powder were obtained from the SCI Materials Hub.
Commercial 20% Pt/C, 40% Pt/C and IrO2 catalysts were also obtained from SCI Materials Hub.
3. Journal of Energy Chemistry Vanadium oxide nanospheres encapsulated in N-doped carbon nanofibers with morphology and defect dual-engineering toward advanced aqueous zinc-ion batteries
In this paper, carbon cloth (W0S1011) was obtained from SCI Materials Hub. The flexible carbon cloth matrix guaranteed the stabilization of the electrode and improved the conductivity of the cathode.
4. Energy Storage Materials Defect-abundant commercializable 3D carbon papers for fabricating composite Li anode with high loading and long life
The 3D carbon paper (TGPH060 raw paper) were purchased from SCI Materials Hub.
5. Nanomaterials A Stable Rechargeable Aqueous Zn–Air Battery Enabled by Heterogeneous MoS2 Cathode Catalysts
Nafion D520 (5 wt%), and carbon paper (GDL340) were received from SCI-Materials-Hub.
Carbon cloth (W0S1011) and other electrochemical consumables required for air cathode were provided by SCI Materials Hub.
The Zn sheet (99.99%) was purchased from SCI Materials Hub.
8. Nature Communications Atomic-scale regulation of anionic and cationic migration in alkali metal batteries
The lithium metal disk (purity: 99.9%, diameter: 16 mm, thickness: 0.6 mm) was obtained from SCI Materials Hub.
9. Chemical Engineering Journal Zinc-based energy storage with functionalized carbon nanotube/polyaniline nanocomposite cathodes
CNTs were purchased from SCI Materials Hub.
10. ACS Nano Interfacial Chemistry Modulation via Amphoteric Glycine for a Highly Reversible Zinc Anode
Zn foil (>99.99%, 100 μm) was purchased from SCI Materials Hub.
11. ACS Nano High-Energy and Long-Lived Zn–MnO2 Battery Enabled by a Hydrophobic-Ion-Conducting Membrane
Zn foil (99.9%), carbon paper, and carbon felt were obtained from SCI Materials Hub.
12. Nature Communications Unravelling rechargeable zinc-copper batteries by a chloride shuttle in a biphasic electrolyte
Carbon cloth (CeTech W0S1011), PP membrane (Celgard 2300), Glass fiber (Whatman GF/A), anion exchange membrane (Fumasep FAB-PK-130), and cation exchange membrane (Nafion N-117) were purchased from sci materials hub.
13. PROCEEDINGS OF SPIE A dendrite-free and corrosion-suppressive metallic Zn anode regulated by the hybrid aqueous/organic electrolyte
Zn foil (99.9%, 100 μm thickness) was obtained from the SCI Materials Hub.
14. Journal of Alloys and Compounds Cr-induced enhancement of structural stability in δ-MnO2 for aqueous Zn-ion batteries
The Zn sheet (99.99%) and Whatman GF/D paper were available for purchase on on the SCI Materials Hub.
Carbon coating aluminum foils with a thickness of 16 µm were acquired from SCI Materials Hub.
16. Journal of Industrial and Engineering Chemistry Investigation into electrochemical catalytic properties and electronic structure of Mn doped SrCoO3 perovskite catalysts
KB-EC600JD superconducting carbon black was obtained from SCI Materials Hub.
17. Journal of Alloys and Compounds Inhibiting polysulfide shuttle and enhancing polysulfide redox: Conductive 2D metal-organic framework coated separators for lithium-sulfur batteries
Ketjen black was obtained from SCI Materials Hub
18. Chemical Engineering Journal Regulating N-doped biochar with Fe-Mo heterojunctions as cathode in long-life zinc-air battery
Conductive carbon black (Vulcan XC-72R) was purchased from SCI Materials Hub (Wuhu, Anhui).
19. Nature Portfolio Fast-kinetics and high-compatibility aqueous cadmium-metal battery for next-generation energy storage infrastructures (Under review.)
Cd foil (99.9%), Zn foil (99.9%) and polytetrafluoroethylene (PTFE) aqueous dispersion solution were obtained from the supplier of SCI Materials Hub.
All cells were assembled using two-electrode Swagelok-type configurations, supported by SCI Materials Hub.
Celgard 2400 separator (polypropylene (PP), 25 μm) was sourced from SCI Materials Hub.
21. ACS Applied Energy Materials 3D Graphene Nanoflake/Vertically Aligned Carbon Nanotube/CoAl Layered Double Oxide Composites for High-Performance Lithium-Ion Batteries
Carbon-coated aluminum foil was procured from SCI Materials Hub.
22. Chemistry A European Jouranl Regulating the Interfacial Charge Density by Constructing a Novel Zn Anode-Electrolyte Interface for Highly Reversible Zn Anode
Ketjenblack (KB) was purchased from SCI Materials Hub
23. Advanced Functional Materials A Biphasic Membraneless Zinc-Iodine Battery with High Volumetric Capacity
Graphite felt (GF, G650A) was purchased from SCI Materials Hub.
24. Science Advances Alcohol molecule coupling: A universal approach to modulating amorphousness in vanadium-based cathodes for high-rate and durable aqueous zinc-ion batteries
Fueiceel® BM03 Battery test hardware in Figure 6F was obtained from SCI Materials Hub. The Fueiceel® BM03 scale-up battery powering an LED panel.
25. Nature Communications Cooperative Jahn-Teller effect and engineered long-range strain in manganese oxide/graphene superlattice for aqueous zinc-ion batteries
The Zn||MnO2 coin cells were assembled by Zn foil (thickness of 0.1 mm, 99.99%, SCI Materials Hub) counter electrodes
26. Adv. Funct. Mater. Construction of Ionic Conductive Electrode/ Electrolyte Interphases via Li+ Coordination Regulator for 4.7 V Li/ LiNi0.9Co0.05Mn0.05O2 Batteries
The CR2032 coin cells were assembled with a Celgard 2400 separator (SCI Materials Hub.) in a glove box.
27. Journal of Energy Storage Bacterial cellulose mixed with glass fiber as a separator to achieve long cycle life of aqueous zinc-ion batteries
304 stainless steel foil (99.99 % purity, purchased from SCI Materials Hub)
28. Nature Communications Dual-structure-breaking electrolyte enables practical cadmium-metal battery
Two-electrode (Swagelok2E002) and three-electrode (Swagelok3E2e) Swagelok-type configurations were supported by SCI Materials Hub (Supplementary Figs. 102, 103)
The stacked configuration (BM03) for the scaled-up cell was supported by SCI Materials Hub.
Cd foil (99.9%), Zn foil (99.9%), and polytetrafluoroethylene (PTFE) aqueous dispersion solution (D-210C, solid content: 60 w%, size: ~0.25 μm size) were obtained from the supplier of SCI Materials Hub.
29. Nature Nanotechnology A nanoengineered lithium-hosting carbon/zinc oxide composite electrode material for efficient non-aqueous lithium metal batteries
The operando battery pressure sensing equipment (BS01) was purchased from SCI Materials Hub (www.scimaterials.cn).
Nafion 115 membrane (N115) was purchased from SCI Materials Hub.
电解水
1. International Journal of Hydrogen Energy Gold as an efficient hydrogen isotope separation catalyst in proton exchange membrane water electrolysis
The cathodic catalysts of Pt/C (20 wt%, 2–3 nm) and Au/C (20 wt%, 4–5 nm) were purchased from SCI Materials Hub.
2. Small Science Silver Compositing Boosts Water Electrolysis Activity and Durability of RuO2 in a Proton-Exchange-Membrane Water Electrolyzer
Two fiber felts (0.35 mm thickness, SCI Materials Hub) were used as the porous transport layers at both the cathode and the anode.
3. Advanced Functional Materials Hierarchical Crystalline/Amorphous Heterostructure MoNi/NiMoOx for Electrochemical Hydrogen Evolution with Industry-Level Activity and Stability
Anion-exchange membrane (FAA-3-PK-130) was obtained from SCI Materials Hub.
4. Chemical Engineering Journal Electronic configuration of single ruthenium atom immobilized in urchin-like tungsten trioxide towards hydrazine oxidation-assisted hydrogen evolution under wide pH media
The non-reinforced anion exchange membrane (AEM) of the coupled system was obtained from SCI Materials Hub (Fumasep FAA-3-50).
5. Cell Reports Physical Science Non-layered dysprosium oxysulfide as an electron-withdrawing chainmail for promoting electrocatalytic oxygen evolution
Nickel foam (NF) was offered by SCI Materials Hub (Wuhu, China), and was ultrasonicated in HCl solution, ethanol, and acetone in proper order before being used in electrochemical measurements.
6. Materials Today Catalysis Valence engineering via double exchange interaction in spinel oxides for enhanced oxygen evolution catalysis
Commercial Cu foam was purchased from SCI Materials Hub.
7. Advanced Functional Materials Elucidating the Critical Role of Ruthenium Single Atom Sites in Water Dissociation and Dehydrogenation Behaviors for Robust Hydrazine Oxidation-Boosted Alkaline Hydrogen Evolution
The nonreinforced anion exchange membrane (AEM) of the HzOR-assisted OWS system was purchased from SCI Materials Hub (Fumasep FAA-3-50).
8. ACS Omega Boosting Hydrogen Evolution through the Interface Effects of Amorphous NiMoO4–MoO2 and Crystalline Cu
Pt/C (20 wt %) was purchased from SCI Materials Hub.
9. Journal of Colloid and Interface Science The Dual Active Sites Reconstruction on Gelatin In-Situ Derived 3d Porous N-Doped Carbon for Efficient and Stable Water Splitting
Nafion D521 was purchased from SCI Materials Hub.
10. Molecules Interfacial Interaction in NiFe LDH/NiS2/VS2 for Enhanced Electrocatalytic Water Splitting
Carbon cloth (SCI Materials Hub) were employed as substrates for the in-situ formation of VS2 and NiS2/VS2 on its surface via hydrothermal synthesis.
11. Chemical Engineering Journal Mapping hydrogen evolution activity trends of V-based A15 superconducting alloys
Carbon fiber paper (GDS250) was obtained from the SCI materials Hub.
12. Advanced Science A Dual-Cation Exchange Membrane Electrolyzer for Continuous H2 Production from Seawater
The CEMs include GORE-SELECT Gore M788.12 (W. L. Gore & Associates, America) and FUMA Fumasep FKB-PK-130 (FuMa Tech., Co., Ltd., Germany) were provided by SCI Materials Hub.
13. Ind. Eng. Chem. Res. Electrolysis of Tertiary Water Effluents - a Pathway to Green Hydrogen
The PEM electrolyzer stack PSC2000 was purchased from the SCI Materials Hub with a maximum hydrogen production capability of 2000 mL/min. The stack had 8 electrolysis cells with a maximum recommended operation current of 36 A and a voltage of 24 V. Its membrane electrode assembly had an effective area of 56 cm2 per layer and a catalyst loading of 4.0 mg/cm2 on Nafion 117 for Ir black as anode and Pt/C as cathode, respectively. The catalysts were deposited on the Nafion membrane to form a catalyst-coated membrane. Titanium bipolar plates were used to construct the electrolyzer. Water is supplied to the anode side of the electrolyzer stack during operation.
14. Adv. Energy Mater. High-Efficiency Iridium-Yttrium Alloy Catalyst for Acidic Water Electrolysis
Carbon paper (Toray TGP-H-060) was purchased from the SCI Materials Hub.
15. Journal of Alloys and Compounds Amorphous/Crystalline Nife Ldh Hierarchical Nanostructure for Large-Current-Density Electrocatalytic Water Oxidation
The commercial NiFe foam (NFF) was offered by SCI Materials Hub.
W0S1009 Carbon cloth (CC, SCI Materials Hub) were employed as substrate for the in-situ formation of Ru-VS2 and VS2 on its surface via hydrothermal synthesis.
17. Journal of Colloid and Interface Science The dual active sites reconstruction on gelatin in-situ derived 3D porous N-doped carbon for efficient and stable overall water splitting
Nafion D521 was purchased from SCI Materials Hub.
18. Journal of Physics and Chemistry of Solids AgCo bimetallic cocatalyst modified g-C3N4 for improving photocatalytic hydrogen evolution
Nafion D520 dispersion (5 wt%) was purchased from SCI Materials Hub.
19. Separation and Purification Technology NiP2 as an efficient non-noble metal cathode catalyst for enhanced hydrogen isotope separation in proton exchange membrane water electrolysis
Ni supported on Vulcan XC-72, obtained from SCI materials Hub.
20. ACS Appl. Nano Mater. Rapid Electrical-Field-Enhanced Corrosion Endows Ni3Fe/NiFe Layered Double Hydroxide Nanosheets with High-Rate Oxygen Evolution Activity
The Ni3Fe substrate obtained directly from a commercial NiFe foam (nominal Ni 70% at. % + Fe 30 at. %, thickness: 2 mm, porosity: 100 PPI, SCI Materials Hub) was cleaned with acetone, ultrapure water, and ethanol successively and was dried with compressed air.
The proposed thin V-Zirfon separator samples were evaluated at first by water electrolysis at 60 °C using a two-compartment zero-gap electrolyzer (LSCF Alkaline Water Electrolyzer stack [1 cell], purchased from SCI Materials Hub).
22. ACS Materials Lett. Promoting Nonacid Hydrogen Evolution over Ni4Mo/Cu by D-Band Regulation
Commercial Pt/C (20%) from Wuhu Eryi Material Technology Co., Ltd.
Note: Wuhu Eryi Material Technology Co. is a company hold by SCI Materials Hub.
23. Molecules Interfacial Interaction in NiFe LDH/NiS2/VS2 for Enhanced Electrocatalytic Water Splitting
Carbon cloth (CC, SCI Materials Hub) were employed as substrates for the in-situ formation of VS2 and NiS2/VS2 on its surface via hydrothermal synthesis.
24. Nat. Commun. Flexible tungsten disulfide superstructure engineering for efficient alkaline hydrogen evolution in anion exchange membrane water electrolysers
Commercial IrO2, Pt/C (40 wt%), anion exchange membrane (Sustainion X37-50 Grade 60) and carbon fiber cloth (CFC) were obtained from SCI Materials Hub.
25. International Journal of Hydrogen Energy Enhancing performance of anion exchange membrane electrolyzer through modification of carbon paper liquid-gas diffusion layer
The anode is made of Ni–Fe foam (60% Fe + 40% Ni, SCI Materials Hub, China), while the cathode is made of carbon paper electrode. AEM employed is the highly stable PiperION™-A40-HCO3 (with a thickness of 40 μm).
26. Nature Communications Rationally designed Ru catalysts supported on TiN for highly efficient and stable hydrogen evolution in alkaline conditions
Fumasep FAAM-20 anion exchange membrane was purchased from SCI Materials Hub.
27. Nature Communications Redox-mediated decoupled seawater direct splitting for H2 production
Nickel foam (Ni Foam, aperture: 110 ppi, area density: 380 ± 20 g cm−2), platinum carbon (Pt/C, 20 wt%), anion exchange membranes (FAA-3-PK-75), graphite felt (thickness: ~2 mm), and commercial alkaline water electrolyzers were purchased from SCI Materials Hub.
28. ACS Applied Materials & Interface Promoting Reaction Kinetics of the Air Cathode for Neutral Zinc–Air Batteries by the Photothermal Effect
Carbon paper (SGL Carbon Sigracet 22BB) was purchased from SCI Materials Hub.
29. International Journal of Hydrogen Energy Efficient and stable formaldehyde-polyoxometalate battery for dual-decoupled hydrogen production
Firstly, the surface of the Cu foam (1 × 1 cm2, Sci Materials Hub Co.) was oxidized into Cu(OH)2 nanowires (denoted as sample Cu(OH)2 NWs/Cu foam) by (NH4)2S2O8 (0.13 M) in 2.67 M NaOH aqueous solution for 30 min at room temperature.
30. International Journal of Hydrogen Energy Controlled deposition of trimetallic Fe–Ni–V oxides on nickel foam as high-performance electrocatalysts for oxygen evolution reaction
Nickel foam (95–98% porosity, 40 pores/cm), manufactured by SCI Materials Hub, was employed for catalyst fabrication.
31. Journal of Alloys and Compounds Cobalt-doping mediated low-valence Rh centers in rhodium sulfide superconductor for improved electrocatalytic hydrogen evolution
Carbon fiber paper (Spectracarb 2050 A, thickness of 10μm, density of 0.50 g cm−3) was purchased from SCI Materials Hub.
32. J. Mater. Chem. A Promoted surface reconstruction of amorphous nickel boride electrocatalysts by boron dissolution for boosting oxygen evolution reaction
The ink was also sprayed onto a 1.5 mm-thick Ni foam substrate (SCI Materials Hub, China).
33. Advanced Energy Materials Surface Reconstruction Activates Non-Noble Metal Cathode for Proton Exchange Membrane Water Electrolyzer
34. J. Mater. Chem. A Multimetallic layered double hydroxides as efficient and durable oxygen evolution catalysts for anion exchange membrane water electrolysis at high current densities
35. Nano Research Hierarchical NiFe LDH/N-doped Co/nickel foam as highly active oxygen evolution reaction electrode for anion exchange membrane water electrolysis
Commercial PtRu/C and RuO2 were purchased from SCI Materials Hub.
36. J. Mater. Chem. A Ga doping Enhances Oxygen Evolution Reaction Performance and stability of NiFe layered double hydroxides
Nickel foam (NF) was purchased from SCI Materials Hub (99.9%,bore diameter 200-250um, thickness 0.3mm).
37. Journal of Industrial and Engineering Chemistry Optimizing CoFe2O4 coatings on nickel foam via Aerosol-Assisted CVD for superior electrochemical oxygen evolution Catalysis
To fabricate the catalyst, we used nickel foam (95–98 % porosity, with 40 pores/cm) produced by SCI Materials Hub
38. International Journal of Hydrogen Energy Experimental and simulation study of H2 crossover in PEM water electrolysis for high-pressure hydrogen production up to 20 MPa
The high-pressure PEMWE cell used a PFSA membrane (Nafion® 117, DUPONT) coated with 0.75 mg cm−2 of Pt/C (40 %, JOHNSON MATTHEY) on the cathode and 1 mg cm−2 of IrO2 (Accelerate®, SCI-MATERIALS HUB) on the anode.
39. Journal of Alloys and Compounds Ruthenium-mediated synthesis of ultrafine FePtCoNiRu high-entropy alloy nanoparticles for enhanced hydrogen evolution catalysis
Vulcan XC-72R (Ketjen Black) was purchased from SCI Materials Hub.
40. Nano-Micro Letters A Strongly Coupled Cluster Heterostructure with Pt–N-Mo Bonding for Durable and Efficient H2 Evolution in Anion-Exchange Membrane Water Electrolyzers
Carbon paper and anion-exchange membrane (PiperION A40) were obtained from SCI Materials Hub.
41. Journal of Alloys and Compounds N, P-doped coconut shell activated carbon supported Mo2C catalysts for alkaline water electrolysis hydrogen evolution
Nafion solution (D520, 5 wt%) was obtained from SCI Materials Hub.
42. Nature Communications Lanthanum-assisted lattice anchoring of iridium in Co3O4 for efficient oxygen evolution reaction in low-iridium water electrolysis
Carbon paper was obtained from SCI Materials Hub.
43. Nanoscale Two-dimensional 1T-phase MnxIr1−xO2 for high-performance acidic oxygen evolution reaction
Commercial Nafion NR212 films were purchased from SCI Materials Hub.
44. Journal of Physics: Conference Series Stability and durability of nickel-molybdenum foam electrodes in electrocatalytic seawater splitting
The Materials used in the present investigation were prepared by SCI Materials Hub.
电 催 化
1. Nature Communications Electrochemical epoxidation enhanced by C2H4 activation and hydroxyl generation at the Ag/SnO2 interface
Fumion FAA anion exchange resin and FAA-3-50 membranes with a thickness of 50 µm were purchased from SCI Materials Hub.
燃料电池
1. Polymer Sub-two-micron ultrathin proton exchange membrane with reinforced mechanical strength
Gas diffusion electrode (60% Pt/C, Carbon paper) was purchased from SCI Materials Hub.
Fumion FAA-3-solut-10 was obtained from SCI Materials Hub.
3. Journal of Power Sources Boosting the power density of the H3PO4/polybenzimidazole high-temperature proton exchange membrane fuel cell to >1.2 W cm-2 via the deposition of acid-based polymer layers on the catalyst layers
PBI resin (molecular weight: 60000, SCI Materials Hub), carbon paper 39BB (SGL Carbon), 70 wt% Pt/C (TANAKA) were obtained from SCI Materials Hub.
Fumasep FAA-3-20 was obtained from SCI Materials Hub.
5. ACS Sustainable Chem. Eng. Vanadium-Mediated High Areal Capacity Zinc–Manganese Redox Flow Battery
Zinc plate (thickness 1 mm), copper foam (thickness 1.5 mm), and Ketjenblack (KB) EC-600JD were procured from SCI materials hub.
6. ACS Appl. Energy Mater. Investigation of Pd2B- and NiB-Doped Pd–Ni/C Electrocatalysts with High Activity for Methanol Oxidation
Nafion solution (5 wt %, DuPont) was purchased from SCI Materials Hub.
7. Chemical Engineering Journal Loosened Hydrophobic Microphase to Facilitate Ion Channel Formation in Anion Exchange Membrane for Fuel Cell Applications
Fumasep FAA-3-20 was obtained from SCI Materials Hub.
8. Energy Conversion and Management: X Amplified impact of contact uniformity on the performance of low-catalyst-loading fuel cells
Commercial Pt/C (weight ratio of Pt, 5 %), commercial Pt/C (weight ratio of Pt, 10 %), carbon black (Ketjenblack EC-300 J), the expanded polytetrafluoroethylene (ePTFE) reinforced proton exchange membranes (PEM) (manufactured by GORE), and GDL were purchased from SCI Materials Hub.
9. ACS Sustainable Chemistry & Engineering Lignin-Derived Sustainable Cationic Polymers for Efficient High-Temperature Proton Exchange Membrane Fuel Cells
Poly-2,2′-(m-phenylene)-5,5′-bibenzimidazole (PBI, Figure 1a) [(MW)RU ∼ 308 g/mol, Mw ∼ 60,000 g/mol, Tg ∼ 427 °C] was purchased from SCI Materials Hub (China).
10. Journal of Energy StorageAnion-type solvation structure enables stable zinc‑iodine flow batteries
The Nafion 115 produced by Dupont was purchased from SCI Materials Hub and pretreated by the standard acid boiling procedure.
11. Chemical Engineering Journal A novel biofuel cell based on galactose oxidase and bilirubin oxidase for efficient glycerol conversion and electricity generation
W1S1011 carbon cloth (CC) with PTFE&MPL (CeTech) was purchased from SCI Materials Hub (China).
12. ACS Nano Improving Fuel Cell Performance of FeNx-Based Catalysts by Introducing Graphitic Microdomains in the Carbon Matrix
13. Science Advances Manipulating the coordination dice: Alkali metals directed synthesis of Co-N-C catalysts with CoN4 sites
A Nafion D521 dispersion (5 wt %, equivalent weight = 1100), PtRu-C (60% PtRu on high–surface area carbon, Pt:Ru = 1:1, SCI Materials Hub), an alkaline ionomer dispersion (PiperION-A5-HCO3-EtOH, 5 wt %, Versogen Inc.), and anion exchange membrane (PiperION-A type-HCO3, Versogen Inc.) were obtained from SCI Materials Hub.
催化-ORR
1. J. Chem. Eng. Superior Efficiency Hydrogen Peroxide Production in Acidic Media through Epoxy Group Adjacent to Co-O/C Active Centers on Carbon Black
In this paper, Vulcan XC 72 carbon black, ion membrane (Nafion N115, 127 μL), Nafion solution (Nafion D520, 5 wt%), and carbon paper (AvCarb GDS 2230 and Spectracarb 2050A-1050) were purchased from SCI Materials Hub.
2. Journal of Colloid and Interface Science Gaining insight into the impact of electronic property and interface electrostatic field on ORR kinetics in alloy engineering via theoretical prognostication and experimental validation
The 20 wt% Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) were purchased from SCI Materials Hub. This work places emphasis on the kinetics of the ORR concerning Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) catalysts, and integrates theoretical prognostication and experimental validation to illuminate the fundamental principles of alloy engineering.
3. Catalysis Solution-Phase Synthesis of Co-N-C Catalysts Using Alkali Metals-Induced N-C Templates with Metal Vacancy-Nx sites
In this paper, PtRu-C (60 % PtRu (3.5nm) on High Surface Area Carbon, Pt:Ru = 1:1, SCI Materials Hub), an alkaline dispersion (PiperION-A5-HCO3-EtOH, 5 wt.%, SCI Materials Hub), anion exchange membrane (PiperION-A type-HCO3, SCI Materials Hub) were used as received.
4. Green Chemistry Low Cell Voltage Electrosynthesis of Hydrogen Peroxide
The proton exchange membranes (Nafion-117, 211, and 212) were from SCI Materials Hub. They were pre-treated by 5 v/v% H2O2 solution for 1 h at 80°C and then treated by 10 v/v% H2SO4 aqueous solution for 1 h at 80°C before assembling to flow cell reactor.
5. Chemosphere Sustainable H2O2 production in a floating dual-cathode electro-Fenton system for efficient decontamination of organic pollutants
Ketogen black (EC-600JD) was purchased from SCI Materials Hub.
6. Journal of Materials Science Carbon dot intercalated MXene with an excellent oxygen reduction reaction electrocatalytic performance
Nafion (5 wt%) was purchased from SCI Materials Hub (Nafion D520).
7. Nature Commuinications Precisely designing asymmetrical selenium-based dual-atom sites for efficient oxygen reduction
Vulcan XC-72R carbon black (CAS No.: 1333-86-4, SCI Materials Hub).
8. ChemElectroChem Balancing the Aggregation of Cobalt Phthalocyanine on Carbon Nanohorn for Efficient H2O2 electrosynthesis in Neutral Electrolyte
AvCarb GDS 2230 substrates and Nafion 1110 membranes were purchased from Sci Materials hub.
Nafion solution (D520, 5 wt%) and proton exchange membrane (PEM, Nafion N117) were purchased from Sci Materials Hub.
Carbon cloth (W0S1011) was purchased from SCI Materials Hub.
11. Nature Portfolio Carbon defects enhanced TEMPO redox cycles for high-efficiency urotropine electrosynthesis
TGPH060H hydrophilic carbon paper (CP), VXC-72 carbon black (CB), nickel foam, Nafion D520 dispersion, Nafion N117, and Fumasep FAA-3-PK-75 were gained from SCI Materials Hub.
12. American Institute of Chemical Engineers A tandem electro-thermocatalysis platform for practical hydrogen peroxide-mediated oxygenation reactions at high rates
Sustainion ionomerbinder solution and anion-exchange membrane (AEM, SustainionX37-50 grade 60) was purchased from SCI Materials Hub.
13. Journal of Environmental Chemical Engineering Metal-free heterogeneous electro-Fenton with solid polymer electrolytes: A novel self-supporting system for PPCPs decontamination
Industrial-grade graphite felt (GF) and solid polymer electrolytes (Nafion®N324, N438, N117, and N115) were procured from SCI Materials Hub.
14. Physical Chemistry Chemical Physics Tailoring LaBO3 (B = Mn, Fe, Co, Ni) perovskite oxides for methanol-tolerant oxygen reduction reaction electrocatalysts
Nafion D520 dispersion (5 wt%) was obtained from SCI Materials Hub.
15. Nano Research Surface diffusion-Limited dealloying: A strategy for porosityconstruction in small-sized alloy nanoparticle electrocatalysts
Commercial 20%Pt/C (TKK-TEC-10E20E) was obtained from SCl MaterialsHub.
电容器
1. Journal of Energy Storage Unraveling the detrimental crosstalk between cathode and anode in the aqueous asymmetric capacitor of activated carbon /copper oxide
In this paper, Fumasep FAA-3-50 anion exchange membrane (Thickness 50 μm, surface resistance 0.6–1.5 Ω cm−2, transference number 92–96 %) was bought from SCI Materials Hub.
2. Composites Science and Technology High modulus carbon fiber based composite structural supercapacitors towards reducing internal resistance and improving multifunctional performance
The aluminium tape (Wuhu Eryi Materials Co. LTD) were used as the current collectors.
Note: Wuhu Eryi Material Technology Co. is a company hold by SCI Materials Hub.
Carbon cloth (CeTech W0S1011) was sourced from SCI Materials Hub.
4. ACS Applied Materials & Interfaces Green Polymer Derived Multifunctional Layer Achieving Oriented Diffusion and Controllable Deposition of Zn2+ for Ultra-Durable Zinc-Ion Hybrid Supercapacitors
Zn foil (99.99%) and Copper foil (99.99%) was purchased from SCI Materials Hub.
5. Journal of Water Process Engineering Enhanced electrodialysis by electric double-layer capacitors to minimize membrane use in digestate ammonia recovery: mechanisms and effects
Carbon cloth (W0S1011, >98 %), cation-exchange membrane (FKB-PK-130, with a thickness of 130 μm) were purchased from SCI Materials Hub.
6. ACS Applied Materials & Interfaces Mechano-Electrochemical Synergy of Lignin Cross-Linked PVA Gel Polymer Electrolytes for Wide-Temperature Flexible Supercapacitors
Raw carbon cloth (CeTech W0S1009) was acquired from SCI Materials Hub
催化加氢
1. Nature Communications Electrosynthesis of polymer-grade ethylene via acetylene semihydrogenation over undercoordinated Cu nanodots
In this paper, activated carbon (Vulcan XC-72) was obtained from SCI Materials Hub.
2. Applied Catalysis B: Environment and Energy Spatial-confined effect of CuOx microneedles bundles on TiO2 nanotubes: Reinforcing the adsorption and enrichment of ultralow concentration nitrate for efficient NH3 electrosynthesis
Ion membrane (Nafion N115, 127 μL) was purchased form Sci Materials Hub.
3. Nature Communications Electrosynthesis of NH3 from NO with ampere-level current density in a pressurized electrolyzer
The anion exchange membrane (Fumasep FAB-PK-130, 130 μm) was purchased from SCI Materials Hub.
4. Sustainable Energy Fuels Dibenzyl ether-guided microstructural regulation of PtIrZn catalysts for ammonia electrocatalysis
5. Chemical Engineering Journal Enhanced electrocatalytic nitrate reduction to ammonia via boron-doped copper foam
Ni foam was purchased from the Sci Materials Hub Co., Ltd. (Anhui, China).
6. Nature Communications Modulating Ru-Co bond lengths in Ru1Co single-atom alloys through crystal phase engineering for electrocatalytic nitrate-to-ammonia conversion
Nafion 211 membrane (diameter: 3 cm, thickness: 25.4 μm) was purchased from SCI Materials Hub.
7. Nature Communications Revealing and modulating catalyst reconstruction for highly efficient electrosynthesis of ammonia
Toray Carbon Paper (CP, TGP-H-060), Nafion 211 membrane, Nafion N117 membrane, and membrane electrode device were obtained from the Sci materials hu
Hydrophilic carbon paper and carbon black, carbon rod electrode was purchased from SCI Materials HUB
9. Separation and Purification Technology A novel membrane-free ion enrichment electrolyzer recovers ammonia from digestate
Carbon cloth (W0S1011, >98 %), cation-exchange membrane (FKB-PK-130, with a thickness of 130 μm), and anion-exchange membrane (FAS-PET-130, with a thickness of 130 μm) were purchased from SCI Materials Hub.
水处理
1. Water Research Electro-peroxone with solid polymer electrolytes: A novel system for degradation of plasticizers in natural effluents
In this paper, Nafion® N324 (SCI Materials Hub), between a 15 cm2 (3 cm × 5 cm) graphite plate anode and a graphite felt cathode (EP-SPE system)
表征
1. Chemical Engineering Journal Electrochemical reconstitution of Prussian blue analogue for coupling furfural electro-oxidation with photo-assisted hydrogen evolution reaction
An Au nanoparticle film was deposited on the total reflecting plane of a single reflection ATR crystal (SCI Materials Hub, Wuhu, China) via sputter coater.
理论计算
1. Sustainable Energy & Fuels A desulfurization fuel cell with alkali and sulfuric acid byproducts: a prototype and a model
A Fumasep®FKD-PK-75 membrane was used as the cation exchange membrane, in which the the oxygen permeability of membrane was about 1 cm3(STP)/(s cm2 cm Hg) [Ref. SCI Materials Hub]
器件
1. Journal of Materials Science: Materials in Electronics Preparation and application of electrical conductive composites with skin temperature-triggered attachable and on-demand detachable adhesion
Carbon black (CB, Ketjenblack EC 600JD) was purchased from SCI Materials Hub.
2. Chemosphere Highly Sensitive Electrochemical Sensor for Lead Ion Based on Bi-Mof/Conducting Polymer Composites
Nafion D520 Dispersion (Alcohol based 1000 EW at 5wt%) was purchased from SCI Materials Hub.
3. ACS Nano High-Performance Graphdiyne Oxide/Au Nanoparticle Electrode for Electrochemical Non-enzymatic Glucose Sensor
Carbon cloth was purchased from SCI Materials Hub (CeTech W0S1011).
材料合成
1. Acta Materialia In situ epitaxial thickening of wafer-scale, highly oriented nanotwinned Ag on tailored polycrystalline Cu substrates
Single-crystal Cu (1 cm × 1 cm) substrates with a (111) orientation were purchased from SCI Materials Hub.
2. Journal of The Electrochemical Society One-Pot Electrodeposition of a PANI:PSS/MWCNT Nanocomposite on Carbon Paper for Scalable Determination of Ascorbic Acid
Raw carbon paper was purchased from SCI Materials Hub
3. Polymer Composites Constructing High-Performance Composite Bipolar Plates via Multidimensional Carbon Networks
KB (EC-600JD), Acetylene black (CB11), and Carbon black (XC-72) were purchased from SCI Materials Hub
催化降解
1. Journal of Environmental Chemical Engineering Conversion of CoNiFe-LDH to CoNiFe-MOF/LDH as catalyst for efficient heterogeneous electro-Fenton degradation of sulfonamide antibiotics
The hydrophobic microporous laminated carbon paper (HML-CP) (2 cm × 2.5 cm) was chosen as a cathode and fabricated by Wuhu Eryi Material Technology Co. (Anhui, China).
Note: Wuhu Eryi Material Technology Co. is a company hold by SCI Materials Hub.
2. Nature Communications Scale-up upcycling of waste polyethylene terephthalate plastics to biodegradable polyglycolic acid plastics
Nickle foam (NF) and Nafion N117 were obtained from SCI Materials Hub.
催化电解
1. Chemical Engineering Journal Modulation of energy barrier of reaction steps over S-doped Ni(OH)2/Cu composites to achieve high-performance urea electrolysis catalysts
Commercial Pt/C (20 wt%) was purchased from Wuhu Eryi Material Technology Co., LTD.
Note: Wuhu Eryi Material Technology Co. is a company hold by SCI Materials Hub.
2. Chemical Engineering Journal Efficient Catalysis for Acidic Methanol Oxidation: Exploration of a Low-Platinum Quaternary Alloy Catalyst Via a Two-Step Method
Nafion (5%) was purchased from SCI Materials Hub.
环 境
1. Journal of Materials Research and TechnologyTribocorrosion performance of TC4 anodized/carbon fiber composite in marine environment
Carbon fiber cloth WOS1011H(M) purchased from Wuhu Eryi Materials Technology Co.
Note: Wuhu Eryi Material Technology Co. is a company hold by SCI Materials Hub.
2. Adv. Funct. Mater. Modulating NFO@N-MWCNTs/CC Interfaces to Construct Multilevel Synergistic Sites (Ni/Fe-O-N-C) for Multi-Heavy Metal Ions Sensing
Carbon cloth (W0S1011) was acquired from SCI Materials Hub (www.scimaterials.cn).
热 电
1. Chemical Engineering Journal High power density charging-free thermally regenerative electrochemical flow cycle for low-temperature thermoelectric conversion
The heat exchangers are composed of 20 μm thick titanium foil (SCI Materials Hub), 1 mm thick rubber gasket and 2 cm thick organic glass from the inside to the outside.
其 它
1. Ceramics International Superhydrophobic carbon fiber composite coatings based on TC4 titanium alloy for improving corrosion resistance
Carbon fiber cloth was purchased from SCI Materials Hub.
2. Electrochimica Acta Integrated electrochemically assisted absorbers for the removal of Carbon dioxide
39 BB carbon paper was obtained from SCI Materials Hub.
3. Journal of Hazardous Materials Chain assembly of Rhodococcus bacteria with O-doped g-C3N4 for photocatalysis mediated high-performance partial nitrification: From nitrite resource evolution to device application
Fumasep FAA-3-PK-130, diameter 30 mm, was purchased from SCI Materials Hub.
4. Nature Communications High selectivity framework polymer membranes chemically tuned towards fast anion conduction
Sustainion® X37-50 Grade RT membrane was purchased from SCI Materials Hub, and was pretreated by soaking in 1 M KOH for 24 h according to a reported procedure.
5. Polymer Composites Constructing High-Performance Composite Bipolar Plates via Multidimensional Carbon Networks
KB (EC-600JD), Acetylene black (CB11), and Carbon black (XC-72) were purchased from SCI Materials Hub Co. Ltd. China.
|
为科学研究提供来源广泛的材料 材料合成仪器装置及材料解决方案 备案号:皖ICP备2021011042号-1 |
关于我们 |


